SECTION I - CHEMICAL PRODUCT & COMPANY IDENTIFICATION
Trade Name: Marinite C
MSDS Number:
B-008
Generic Name: Calcium Silicate Board
Revision:5
Manufacturer: BNZ Materials, Inc.
Date Issued: June
4, 2006
Address: 6901 S. Pierce Street, Suite 260
24 hour Emergency Number (ChemTrec®):
800-424-9300
Littleton, CO 80128, USA
SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
CAS Number
%
TLV
PEL
Calcium Silicate
1344-95-2
60-80
10 mg/m3
5 mg/m3
Calcium Metasilicate (Wollastonite)
13983-17-0
20-40
3 mg/m3
5 mg/m3
Man-made reinforcing fibers
None
0-10
None
None
Crystalline Silica (quartz)
14808-60-7
<0.2
0.05 mg/m3
0.1 mg/m3
Crystalline Silica (cristobalite)
14464-46-1
<0.4
0.05 mg/m3
0.05 mg/m3
Key:
TLV = ACGIH, 8 hr. time weighted average (TWA); PEL = OSHA
permissible exposure limit.
TLV and PEL limits are for total respirable (Inhalable)dust.
SECTION III - HAZARDS IDENTIFICATION
Emergency Overview: This product
may flame during initial heat-up if in contact with glowing heating elements.
Airborne particulate created during cutting and handling is considered nuisance
dust and should be minimized through the use of good work practices and adequate
ventilation.
HMIS Rating:
Health: 1*
Fire: 0
Reactivity: 0
Personal Protection: E
WHMIS Class:
D-2A - Material causing other toxic
effects (VERY TOXIC - Chronic)
Primary Routes of Entry: Via respirable
dust to the lungs and respiratory system and via coarse dust and particulate
to the eyes.
Primary Target Organs: Lungs, respiratory
system and eyes.
Potential Health Effects:
Inhalation:: Long term overexposure
to respirable crystalline silica dust may cause permanent and irreversible
lung damage including silicosis.
Skin Contact: Possible dryness
or irritation resulting from long term exposures to product dust.
Eye Contact: A mechanical irritant
which can cause moderate to severe eye irritation.
Ingestion: Non-hazardous when
ingested. Potentially a mild irritant to the GI tract if excessive quantity
is ingested.
Medical Conditions Aggravated by Exposure:
Pre-existing chronic upper respiratory and lung diseases such as, but not
limited to, bronchitis, emphysema and asthma.
Carcinogenicity: This product contains crystalline silica which is classified as a class 1,
human carcinogen by IARC, as a suspect carcinogen by NTP and as a possible select carcinogen by OSHA.
SECTION IV - FIRST AID MEASURES
Inhalation: Remove to fresh air. Drink water
to clear throat and blow nose to evacuate dust. If coughing and irritation
develop, call a physician.
Eye Contact: Flush with large amounts of
water until irritation subsides, at least 15 minutes. See a physician if
irritation persists.
Skin Contact: Normal good personal hygiene
practices. Wash with mild soap and warm water after each exposure.
Ingestion: Emergency procedures not normally
required. May be a temporary irritant to the GI system.
SECTION V - FIREFIGHTING MEASURES
NFPA Rating:
Health: 01
Fire: 0
Reactivity: 0
Other: 0
Flashpoint and Method: This
is a non-flammable product
LEL: N/Ap
UEL: N/Ap
Extinguishing Method:
Not applicable. Product will not burn.
Special Firefighting Procedures:
Not applicable.
Fire or explosion Hazards:
None
SECTION VI - ACCIDENTAL RELEASE MEASURES
Clean-up Procedures: Pick up or
shovel material into waste container taking care to minimize dust. Wet down
if necessary to control dust. Vacuum clean dust with equipment fitted with HEPA
filter.
Personal Precautions: If dusty
conditions exist, wear a face mask approved for use with dusts such as 3M 8511
N-95 or equivalent.
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: When over
PEL/TLV wear an approved face mask such as 3M 8511 N-95 or equivalent, to protect
against silica and pneumoconiosis producing dust. Concentrations of dust that
exceed the recommendations of the dust mask manufacturer will need a higher
level of respiratory protection, such as a half mask respirator with appropriate
dust filters.
Eye Protection: Wear safety glasses
with side shields, goggles or face shield when cutting, milling or abrading
to protect eyes against dust and particulate.
Skin Protection: Under normal conditions
the wearing of protective gloves and clean, body-covering clothing should
be adequate.
Engineering Controls: Maintain
sufficient mechanical or natural ventilation to assure dust concentrations remain
below PEL/TLV. Use local exhaust if necessary. Power equipment should be equipped
with properly designed dust collection devices.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Solid,
off white to gray block of variable size. No characteristic odor.
Melting Point: >2300°
F
Specific Gravity: 0.7 - 1.2
Solubility in Water: Insoluble
Evaporation Rate: N/Ap
SECTION X - REACTIVITY
Stability: Product is stable under normal
conditions.
Hazardous Polymerization: Cannot occur.
Incompatibilities: None in designed use.
Decomposition Products: Decomposition
of residual organic fillers will emit fumes of CO and CO2 during initial exposure
to service temperatures.
Conditions to Avoid: None in designed use.
SECTION XI - TOXICOLOGICAL/ECOLOGICAL INFORMATION
LD50: N/Av
LC50: N/Av
Toxicological Hazards: Some medical
studies of wollastonite mine and mill workers suggest that long term cumulative
exposures to wollastonite dust may cause decreased pulmonary function or mild
industrial bronchitis, particularly in workers who smoke.
Ecological Hazards: Most ingredients
in this product are naturally occurring minerals. Unless contaminated in service,
this product is non-hazardous to the environment.
SECTION XII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: : May be
disposed in an approved landfill unless contaminated in service. If contaminated
with hazardous materials, place waste in suitable container. Seal and properly
label the waste container. Send the container to an approved Transportation,
Storage and Disposal (TSD) facility via an approved waste hauler. Be sure manifests
have been completed and an adequate "Paper trail" has been established.
SECTION XIII - TRANSPORTATION INFORMATION
US DOT Shipping Name: Not regulated
DOT Label: None
UN/NA Number: None
Canadian TGD Shipping Description: Not regulated
as dangerous goods according to Canadian TDGA
International Dangerous Goods Information:
IMO: Not regulated as dangerous
goods according to the IMDG Code.
ICAO: Not regulated as dangerous
goods according to the IACO Technical Instructions.
SECTION XIV - REGULATORY INFORMATION
OSHA Status: This product is considered
hazardous under OSHA criteria.
TSCA/CEPA Status: All components of this
product are included in the TSCA and CEPA Chemical Inventories.
CERCLA Reportable Quantity: N/Ap
SARA Title III:
Section 302 Extremely Hazardous: This product
contains no extremely hazardous substances as defined and listed in section
#302
Section 311/312 Hazard Categories: Reportable
as a hazardous substance. Check with your Local Emergency Planning Committee
for reportable quantities.
Section 313 Toxic Chemicals: This product
does not contain substances which are reportable under Section 313.
WHMIS Information: : WHMIS Classification:
D-2A - Material causing other toxic effects (VERY TOXIC - Chronic). This product
has been classified in accordance with the hazard criteria of the Controlled
Products Regulations (CPR).
Other Regulatory Classifications:
DSCL (EEC):
R36 - Irritating to eyes
R39 - Danger of very serious irreversibel effects
R45 - May cause cancer
SECTION XV - APPROVALS
Reason for Issue:: WHMIS 3 year update
Approval Date: June 4, 2006
Prepared by: CCG, Inc.
Supersedes Date:June 4, 2003
Revision History: Update HMIS Data, May 5, 2002; Change to
Crystalline Silica (quartz) TLV standard (0.05 mg/m3). Removal of Product
Stewardship Information (June 4, 2003).
SECTION XVI - DISCLAIMER
As of the date of this document, the foregoing information is believed
to be accurate and is provided in good faith to comply with applicable federal
and state laws. However, no warranty or representation of law or fact, with
respect to such information, is intended or given.